Functionalization of polyolefins by reactive processing

Cross metathesis functionalization of polyolefins.

A cross metathesis strategy is reported for the post-polymerization functionalization of the pendant vinyl groups present in a range of polyolefin architectures. This represents a general strategy for the synthesis of tailored random and block copolymers as well as homopolymers.

Controlled functionalization of crystalline polyolefins and their application in soluble polymer support

Polyolefins, a Success Story

This paper reports the principal discoveries which have played a major role in the polyolefin field and have positioned polyolefins as the most produced plastics. The early development of polyolefins covering the production of LDPE (Low density polyethylene) at ICI (Imperial Chemical Industries) and the discovery of Phillips or Ziegler-Natta catalysts are highlighted in the first section. In th...

Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds.

Exohedral derivatization of endohedral metallofullerenes (EMFs) has been exploited as a useful method for characterizing the structural and chemical properties of EMFs, and for functionalizing them for potential applications. The introduction of heteroatoms, such as electropositive silicon atoms, to fullerene cages is a novel functionalization method that remarkably affects the electronic chara...

Functionalization of Ti-40Nb implant material with strontium by reactive sputtering

BACKGROUND Surface functionalization of orthopedic implants with pharmaceutically active agents is a modern approach to enhance osseointegration in systemically altered bone. A local release of strontium, a verified bone building therapeutic agent, at the fracture site would diminish side effects, which could occur otherwise by oral administration. Strontium surface functionalization of special...